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The talk will address new materials for perovskite solar cells (PSC) and solid-state dye-sensitised solar cells (ssDSSC). PSCs have brought a paradigm shift in efficiencies of solution based photovoltaics. Triarylamine (TAA)-based materials, especially Spiro-OMeTAD, have been the most promising hole-transport materials (HTM), however Spiro-OMeTAD is one of the most costly layers of the PSCs. Considering this, we have prepared novel triarylamines with varying oxidation potentials and varying alkyl chain length, which exhibit excellent performance when tested in PSCs. Analogues with different oxidation potentials have been studied in both perovskite and solid-state dye-sensitised solar cells to understand the role of driving force in hole extraction. For ssDSSCs, we have also explored a range of new dyes with design that differs from the common donor-pi-acceptor motif that is ubiquitous in the literature.
Professor Neil Robertson is Chair of Molecular Materials at the University of Edinburgh, UK. He is author of around 140 publications on materials for solar energy conversion as well as other optical, conducting and magnetic materials and devices. He was Director of the Scottish Institute for Solar Energy Research 2012-2014 and is the Energy Technology Partnership theme leader for Solar. He is a Fellow of the Royal Society of Chemistry and Associate Editor of Journal of Materials Chemistry C. He acts as Director of Internationalisation for the School of Chemistry, building partnerships with universities in Asia, Europe, North and South America.